What do you mean by "groups?" Do you mean a mail list containing multiple email addresses?
There are no mailing lists in Hotmail, but you can manage groups of people by assigning them to categories.
I can't verify that the actions or steps in MSN Explorer are the same or different as I don't have it running on this PC and haven't used it in a while.
Since MSN email is Hotmail, though, I suspect that performing the actions above at http://www.hotmail.com will yield the desired results in MSN email, too.
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